For the efficient generation of random variates, we use the following useful fact (see e.g. Theorem 19.1 in @Haubold2011a): A standard $\alpha$-Mittag-Leffler random variable $Y$ has the representation:
$$Y \stackrel{d}{=} X^{1/\alpha} Z$$
where $X$ is standard exponentially distributed, $Z$ is $\alpha$-stable with Laplace Transform $$\mathbf E[\exp(-sZ)] = \exp(-s^\alpha),$$ $X$ and $Z$ are independent, and $\stackrel{d}{=}$ means equality in distribution.
n <- 5 x <- rexp(n)
To generate such random variates $Z$, we use
a <- 0.8 sigma <- (cos(pi*a/2))^(1/a) z <- stabledist::rstable(n = n, alpha = a, beta = 1, gamma = sigma, delta = 0, pm = 1)
Below are the details of the calculation. We use the parametrization of the stable distribution by @SamorodnitskyTaqqu as it has become standard. For $\alpha \in (0,1)$ and $\alpha \in (1,2)$,
$$\mathbf E[\exp(it Z)] = \exp\left\lbrace -\sigma^\alpha |t|^\alpha \left[1 - i \beta {\rm sgn}t \tan \frac{\pi \alpha}{2}\right] + i a t\right\rbrace$$
As in @thebook, Equation (7.28), set
$$\sigma^\alpha = C \Gamma(1-\alpha) \cos \frac{\pi\alpha}{2},$$
for some constant $C > 0$, set $\beta = 1$, set $a = 0$, and the log-characteristic function becomes
\begin{align} -C \frac{\Gamma(2-\alpha)}{1-\alpha} \cos \frac{\pi\alpha}{2} |t|^\alpha \left[1 - i\, {\rm sgn}(t) \tan \frac{\pi \alpha}{2}\right] \ = -C \Gamma(1-\alpha)|t|^\alpha \left[ \cos \frac{\pi \alpha}{2} - i\,{\rm sgn}(t) \sin \frac{\pi \alpha}{2}\right] \ = -C \Gamma(1-\alpha)|t|^\alpha\left(\exp(-i {\rm sgn}(t) \pi/2)\right)^\alpha \ = -C \Gamma(1-\alpha)(-i |t| {\rm sgn}(t))^\alpha \ = -C \Gamma(1-\alpha)(-it)^\alpha \end{align}
Setting $t = is$ recovers the Laplace transform, and to match the Laplace transform $\exp(-s^\alpha)$ of $Z$, it is necessary that $C \Gamma(1-\alpha) = 1$. But then $\sigma^\alpha = \cos(\pi \alpha/2)$, and we see that
$$Z \sim S(\alpha, \beta, \sigma, a) = S(\alpha, 1, \cos(\pi\alpha/2)^{1/\alpha}, 0)$$
y <- x^(1/a) * z y
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