View source: R/hilldeboeranalysis.R
hilldeboeranalysis | R Documentation |
Hill-Deboer isotherm model describes as a case where there is mobile adsorption as well as lateral interaction among molecules.The increased or decreased affinity depends on the kind of force among the adsorption molecules. If there is an attraction between adsorbed molecules, there is an increase in affinity. On the other hand, decreased affinity happens when there is repulsion among the adsorbed molecules.
hilldeboeranalysis(Ce, theta, Temp)
Ce |
the numerical value for the equilibrium capacity |
theta |
is the fractional surface coverage |
Temp |
the temperature of the adsorption experimentation in Kelvin |
the nonlinear regression, parameters for the Hill-Deboer isotherm, and model error analysis
Paul Angelo C. Manlapaz
Chester C. Deocaris
De Boer, J. H. (1953). The Dynamical Character of adsorption, Oxford University Press, Oxford, England.
Foo, K. Y., and Hameed, B. H. (2009, September 13). <doi:10.1016/j.cej.2009.09.013> Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal.
theta <- c(0.19729, 0.34870, 0.61475, 0.74324, 0.88544, 0.89007, 0.91067, 0.91067, 0.96114) Ce <- c(0.01353, 0.04648, 0.13239, 0.27714, 0.41600, 0.63607, 0.80435, 1.10327, 1.58223) Temp <- 298 hilldeboeranalysis(Ce,theta, Temp)
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