kiselev.LM: Kiselev Isotherm Linear Analysis

In PUPAIM: A Collection of Physical and Chemical Adsorption Isotherm Models

Kiselev Isotherm Linear Analysis

Description

It is also known as localized monomolecular layer model and is only valid for surface coverage theta > 0.68.

Usage

kiselev.LM(Ce, theta)

Arguments

Ce	the numerical value for equilibrium capacity
theta	is the fractional surface coverage

Value

the linear regression, parameters for the Kiselev isotherm, and model error analysis

Author(s)

Paul Angelo C. Manlapaz

Chester C. Deocaris

References

Kiselev, A. V. (1958). "Vapor adsorption in the formation of adsorbate molecule complexes on the surface," Kolloid Zhur, vol. 20, pp. 338-348.

Examples

Ce <- c(0.01353, 0.04648, 0.13239, 0.27714, 0.41600, 0.63607,
0.80435, 1.10327, 1.58223)
theta  <- c(0.1972984, 0.3487013, 0.6147560, 0.7432401, 0.8854408,
0.8900708, 0.9106746, 0.9106746, 0.9611422)
kiselev.LM(Ce,theta)

PUPAIM documentation built on May 28, 2022, 1:14 a.m.