isochron | R Documentation |
Plots cogenetic U-Pb, Ar-Ar, K-Ca, Pb-Pb, Th-Pb, Rb-Sr, Sm-Nd,
Re-Os, Lu-Hf, U-Th-He or Th-U data as X-Y scatterplots, fits an
isochron curve through them using the york
,
titterington
or ludwig
function, and computes the
corresponding isochron age, including decay constant uncertainties.
isochron(x, ...)
## Default S3 method:
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
xlab = "x",
ylab = "y",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
title = TRUE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
...
)
## S3 method for class 'other'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
xlab = "x",
ylab = "y",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
title = TRUE,
model = 1,
wtype = 1,
anchor = 0,
flippable = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
...
)
## S3 method for class 'UPb'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
joint = TRUE,
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
type = 1,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
show.ellipses = 1 * (model != 2),
anchor = 0,
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
y0option = 1,
taxis = FALSE,
...
)
## S3 method for class 'PbPb'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = TRUE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
growth = FALSE,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
...
)
## S3 method for class 'ArAr'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = TRUE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
...
)
## S3 method for class 'ThPb'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = FALSE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
...
)
## S3 method for class 'KCa'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
inverse = FALSE,
ci.col = "gray80",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
bratio = 0.895,
...
)
## S3 method for class 'RbSr'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = FALSE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
...
)
## S3 method for class 'ReOs'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = FALSE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
...
)
## S3 method for class 'SmNd'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = FALSE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
...
)
## S3 method for class 'LuHf'
isochron(
x,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
inverse = FALSE,
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
taxis = FALSE,
...
)
## S3 method for class 'UThHe'
isochron(
x,
sigdig = 2,
oerr = 3,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
model = 1,
wtype = 1,
anchor = 0,
show.ellipses = 2 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
...
)
## S3 method for class 'ThU'
isochron(
x,
type = 2,
oerr = 3,
sigdig = 2,
show.numbers = FALSE,
levels = NA,
clabel = "",
ellipse.fill = c("#00FF0080", "#FF000080"),
ellipse.stroke = "black",
ci.col = "gray80",
line.col = "black",
lwd = 1,
plot = TRUE,
exterr = FALSE,
model = 1,
wtype = "a",
show.ellipses = 1 * (model != 2),
hide = NULL,
omit = NULL,
omit.fill = NA,
omit.stroke = "grey",
y0option = 4,
...
)
x |
EITHER a matrix with the following five columns:
OR an object of class |
... |
optional arguments to be passed on to |
oerr |
indicates whether the analytical uncertainties of the output are reported in the plot title as:
|
sigdig |
the number of significant digits of the numerical values reported in the title of the graphical output |
show.numbers |
logical flag ( |
levels |
a vector with additional values to be displayed as different background colours within the error ellipses. |
clabel |
label for the colour scale |
xlab |
text label for the horizontal plot axis |
ylab |
text label for the vertical plot axis |
ellipse.fill |
Fill colour for the error ellipses. This can either be a single colour or multiple colours to form a colour ramp. Examples: a single colour: multiple colours: a colour palette: a reversed palette: For empty ellipses, set |
ellipse.stroke |
the stroke colour for the error
ellipses. Follows the same formatting guidelines as
|
ci.col |
the fill colour for the confidence interval of the intercept and slope. |
line.col |
colour of the isochron line |
lwd |
line width |
plot |
if |
title |
add a title to the plot? |
model |
construct the isochron using either:
|
wtype |
controls the parameter responsible for the overdispersion in model-3 regression. If
otherwise,
|
anchor |
control parameters to fix the intercept age or common Pb composition of the isochron fit. This can be a scalar or a vector. If If If |
show.ellipses |
show the data as:
|
hide |
vector with indices of aliquots that should be removed from the plot. |
omit |
vector with indices of aliquots that should be plotted but omitted from the isochron age calculation. |
omit.fill |
fill colour that should be used for the omitted aliquots. |
omit.stroke |
stroke colour that should be used for the omitted aliquots. |
flippable |
controls if generic data (where |
joint |
logical. Only applies to U-Pb data formats 4 and
above. If |
type |
if
if
if
|
exterr |
propagate external sources of uncertainty (J, decay constant)? |
y0option |
controls the type of y-intercept or activity ratio that is reported along with the isochron age. Only relevant to U-Pb data and Th-U data formats 1 and 2. For U-Pb data:
For Th-U data:
|
taxis |
logical. If |
inverse |
toggles between normal and inverse isochrons. If the
isochron plots If If |
growth |
add Stacey-Kramers Pb-evolution curve to the plot? |
bratio |
the |
Given several aliquots from a single sample, isochrons allow the
non-radiogenic component of the daughter nuclide to be quantified
and separated from the radiogenic component. In its simplest form,
an isochron is obtained by setting out the amount of radiogenic
daughter against the amount of radioactive parent, both normalised
to a non-radiogenic isotope of the daughter element, and fitting a
straight line through these points by least squares regression
(Nicolaysen, 1961). The slope and intercept then yield the
radiogenic daughter-parent ratio and the non-radiogenic daughter
composition, respectively. There are several ways to fit an
isochron. The easiest of these is total least squares
regression, which weighs all data points equally. In the presence
of quantifiable analytical uncertainty, it is equally
straightforward to use the inverse of the y-errors as weights. It
is significantly more difficult to take into account uncertainties
in both the x- and the y-variable (York, 1966). IsoplotR
does so for its U-Th-He isochron calculations. The York (1966)
method assumes that the analytical uncertainties of the x- and
y-variables are independent from each other. This assumption is
rarely met in geochronology. York (1968) addresses this issue with
a bivariate error weighted linear least squares algorithm that
accounts for covariant errors in both variables. This algorithm was
further improved by York et al. (2004) to ensure consistency with
the maximum likelihood approach of Titterington and Halliday
(1979).
IsoplotR
uses the York et al. (2004) algorithm for its
Ar-Ar, K-Ca, Pb-Pb, Th-Pb, Rb-Sr, Sm-Nd, Re-Os and Lu-Hf
isochrons. The maximum likelihood algorithm of Titterington and
Halliday (1979) was generalised from two to three dimensions by
Ludwig and Titterington (1994) for U-series disequilibrium dating.
Also this algorithm is implemented in IsoplotR
. Finally, the
constrained maximum likelihood algorithms of Ludwig (1998) and
Vermeesch (2020) are used for isochron regression of U-Pb data. The
extent to which the observed scatter in the data can be explained
by the analytical uncertainties can be assessed using the Mean
Square of the Weighted Deviates (MSWD, McIntyre et al., 1966),
which is defined as:
MSWD = ([X - \hat{X}] \Sigma_{X}^{-1} [X - \hat{X}]^T)/df
where X
are the data, \hat{X}
are the fitted values,
and \Sigma_X
is the covariance matrix of X
, and df
= k(n-1)
are the degrees of freedom, where k
is the
dimensionality of the linear fit. MSWD values that are far smaller
or greater than 1 indicate under- or overdispersed measurements,
respectively. Underdispersion can be attributed to overestimated
analytical uncertainties. IsoplotR
provides three
alternative strategies to deal with overdispersed data:
Attribute the overdispersion to an underestimation of the
analytical uncertainties. In this case, the excess scatter can be
accounted for by inflating those uncertainties by a factor
\sqrt{MSWD}
.
Ignore the analytical uncertainties and perform a total least squares regression.
Attribute the overdispersion to the presence of 'geological scatter'. In this case, the excess scatter can be accounted for by adding an overdispersion term that lowers the MSWD to unity.
If x
has class PbPb
, ThPb
,
ArAr
, KCa
, RbSr
, SmNd
, ReOs
or LuHf
, or UThHe
, returns a list with the
following items:
the intercept of the straight line fit and its standard error.
the slope of the fit and its standard error.
the covariance of the slope and intercept
the degrees of freedom of the linear fit (df=n-2
for non-anchored fits)
a two- or three-element list containing:
y
: the atmospheric ^{40}
Ar/^{36}
Ar or initial
^{40}
Ca/^{44}
Ca, ^{187}
Os/^{188}
Os,
^{87}
Sr/^{87}
Rb, ^{143}
Nd/^{144}
Nd,
^{176}
Hf/^{177}
Hf or ^{208}
Pb/^{204}
Pb
ratio.
s[y]
: the standard error of y
disp[y]
: the standard error of y
enhanced by
\sqrt{mswd}
(only applicable if model=1
).
a three-element list containing:
t
: the ^{207}
Pb/^{206}
Pb,
^{208}
Pb/^{232}
Th, ^{40}
Ar/^{39}
Ar,
^{40}
K/^{40}
Ca, ^{187}
Os/^{187}
Re,
^{87}
Sr/^{87}
Rb, ^{143}
Nd/^{144}
Nd or
^{176}
Hf/^{177}
Hf age.
s[t]
: the standard error of t
disp[t]
: the standard error of t
enhanced by
\sqrt{mswd}
(only applicable if model=1
).
the mean square of the residuals (a.k.a 'reduced
Chi-square') statistic (omitted if model=2
).
the p-value of a Chi-square test for linearity
(omitted if model=2
)
the overdispersion term, i.e. a two-element vector with
the standard deviation of the (assumed) normally distributed
geological scatter that underlies the measurements, and its
standard error (only returned if model=3
).
(only reported if x
has class PbPb
and
growth
is TRUE
) the intercept(s) of the isochron with
the Stacey-Kramers mantle evolution curve.
OR, if x
has class ThU
:
if x$type=1
or x$type=3
: the best fitting
^{230}
Th/^{232}
Th intercept,
^{230}
Th/^{238}
U slope, ^{234}
U/^{232}
Th
intercept and ^{234}
U/^{238}
U slope, OR, if
x$type=2
or x$type=4
: the best fitting
^{234}
U/^{238}
U intercept,
^{230}
Th/^{232}
Th slope, ^{234}
U/^{238}
U
intercept and ^{234}
U/^{232}
Th slope.
the covariance matrix of par
.
the degrees of freedom for the linear fit, i.e. (3n-3)
if
x$format=1
or x$format=2
, and (2n-2)
if
x$format=3
or x$format=4
if type=1
: the ^{230}
Th/^{232}
Th
intercept; if type=2
: the ^{230}
Th/^{238}
U
intercept; if type=3
: the ^{234}
Th/^{232}
Th
intercept; if type=4
: the ^{234}
Th/^{238}
U
intercept and its propagated uncertainty.
if type=1
: the ^{230}
Th/^{238}
U slope;
if type=2
: the ^{230}
Th/^{232}
Th slope; if
type=3
: the ^{234}
U/^{238}
U slope; if
type=4
: the ^{234}
U/^{232}
Th slope and its
propagated uncertainty.
the covariance between a
and b
.
the mean square of the residuals (a.k.a 'reduced Chi-square') statistic.
the p-value of a Chi-square test for linearity.
a three-element vector containing:
y
: the initial ^{234}
U/^{238}
U-ratio
s[y]
: the standard error of y
disp[y]
: the standard error of y
enhanced by
\sqrt{mswd}
.
a two (or three) element vector containing:
t
: the initial ^{234}
U/^{238}
U-ratio
s[t]
: the standard error of t
disp[t]
: the standard error of t
enhanced by
\sqrt{mswd}
(only reported if model=1
).
the overdispersion term, i.e. a two-element vector with the standard deviation of the (assumedly) Normally distributed geological scatter that underlies the measurements, and its standard error.
a matrix with the following columns: the X-variable for the isochron plot, the analytical uncertainty of X, the Y-variable for the isochron plot, the analytical uncertainty of Y, and the correlation coefficient between X and Y.
the x-label of the isochron plot
the y-label of the isochron plot
OR if x
has class UPb
:
if model=1
or 2
, a three element vector
containing the isochron age and the common Pb isotope ratios. If
model=3
, adds a fourth element with the overdispersion
parameter w
.
the covariance matrix of par
the logarithm of par
the logarithm of cov
the number of analyses in the dataset
the degrees of freedom for the linear fit, i.e. 2n-3
the y-intercept and its standard error
the isochron slope and its standard error
the covariance between a
and b
.
the mean square of the residuals (a.k.a 'reduced Chi-square') statistic.
the p-value of a Chi-square test for linearity.
a two or three-element vector containing:
y
: the initial ^{206}
Pb/^{204}
Pb-ratio (if
type=1
and x$format=4,5
or 6
);
^{207}
Pb/^{204}
Pb-ratio (if type=2
and
x$format=4,5
or 6
);
^{208}
Pb/^{206}
Pb-ratio (if type=1
and
x$format=7
or 8
);
^{208}
Pb/^{207}
Pb-ratio (if type=2
and
x$format=7
or 8
);
^{206}
Pb/^{208}
Pb-ratio (if type=3
and
x$format=7
or 8
); or
^{207}
Pb/^{208}
Pb-ratio (if type=4
and
x$format=7
or 8
).
s[y]
: the standard error of y
disp[y]
: the standard error of y
enhanced by
\sqrt{mswd}
(only returned if model=1
)
the y-axis label of the isochron plot
a two (or three) element vector containing:
t
: the isochron age
s[t]
: the standard error of t
disp[t]
: the standard error of t
enhanced by
\sqrt{mswd}
(only reported if model=1
).
the x-label of the isochron plot
the y-label of the isochron plot
OR, if x
has class other
and x$format
is
either 4
or 5
and flippable
is not 0
,
returns
Dd
: the ratio of the inherited radiogenic daughter to its
nonradiogenic sister isotope
DP
: the ratio fo the radiogic daughter to its radioactive parent
cov.DdDP
: the covariance between Dd
and DP
.
In the remaining types of other
data, the intercept a
and b
are returned along with their covariance.
Ludwig, K.R. and Titterington, D.M., 1994. Calculation of
^{230}
Th/U isochrons, ages, and errors. Geochimica et
Cosmochimica Acta, 58(22), pp.5031-5042.
Ludwig, K.R., 1998. On the treatment of concordant uranium-lead ages. Geochimica et Cosmochimica Acta, 62(4), pp.665-676.
Nicolaysen, L.O., 1961. Graphic interpretation of discordant age measurements on metamorphic rocks. Annals of the New York Academy of Sciences, 91(1), pp.198-206.
Titterington, D.M. and Halliday, A.N., 1979. On the fitting of parallel isochrons and the method of maximum likelihood. Chemical Geology, 26(3), pp.183-195.
Vermeesch, P., 2020. Unifying the U-Pb and Th-Pb methods: joint isochron regression and common Pb correction, Geochronology, 2, 119-131.
York, D., 1966. Least-squares fitting of a straight line. Canadian Journal of Physics, 44(5), pp.1079-1086.
York, D., 1968. Least squares fitting of a straight line with correlated errors. Earth and Planetary Science Letters, 5, pp.320-324.
York, D., Evensen, N.M., Martinez, M.L. and De Basebe Delgado, J., 2004. Unified equations for the slope, intercept, and standard errors of the best straight line. American Journal of Physics, 72(3), pp.367-375.
york
,
titterington
,
ludwig
attach(examples)
isochron(RbSr)
fit <- isochron(ArAr,inverse=FALSE,plot=FALSE)
dev.new()
isochron(ThU,type=4)
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