ex12: Example 12-Advective and Diffusive Flux of Heat and Solutes

Description Source References See Also Examples

Description

This example demonstrates the capability of PHREEQC to calculate transient transport of heat and solutes in a column or along a 1D flowline. A column is initially filled with a dilute KCl solution at 25 degrees C in equilibrium with a cation exchanger. A KNO3 solution then advects into the column and establishes a new temperature of 0 degrees C. Subsequently, a sodium chloride solution at 24 degrees C is allowed to diffuse from both ends of the column, assuming no heat is lost through the column walls. At one end, a constant boundary condition is imposed, and at the other end, the final cell is filled with the sodium chloride solution and a closed boundary condition is prescribed. For the column end with a constant boundary condition, an analytical solution is compared with PHREEQC results, for unretarded Cl- (R = 1.0) and retarded Na+ and temperature (R = 3.0). Finally, the second-order accuracy of the numerical method is verified by increasing the number of cells by a factor of three and demonstrating a decrease in the error of the numerical solution by approximately one order of magnitude relative to the analytical solution. The example can be run using the phrRunString routine.

Source

http://wwwbrr.cr.usgs.gov/projects/GWC_coupled/phreeqc

References

http://pubs.usgs.gov/tm/06/a43/pdf/tm6-A43.pdf

See Also

Other Examples: ex10, ex11, ex13a, ex14, ex15, ex16, ex17, ex18, ex19, ex1, ex20a, ex21, ex22, ex2, ex3, ex4, ex5, ex6, ex7, ex8, ex9

Examples

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phreeqc documentation built on July 1, 2020, 11:46 p.m.