R/pH.R

In seacarb: Seawater Carbonate Chemistry

# Copyright (C) 2009 Jean-Pierre Gattuso
#
# This file is part of seacarb.
#
# Seacarb is free software; you can redistribute it and/or modify it under the terms of the GNU General Public License as published by the Free Software Foundation; either version 2 of the License, or any later version.
#
# Seacarb is distributed in the hope that it will be useful, but WITHOUT ANY WARRANTY; without even the implied warranty of MERCHANTABILITY or FITNESS FOR A PARTICULAR PURPOSE.  See the GNU General Public License for more details.
#
# You should have received a copy of the GNU General Public License along with seacarb; if not, write to the Free Software Foundation, Inc., 59 Temple Place, Suite 330, Boston, MA  02111-1307  USA
#
#
"pH" <- 
function(Ex=-67,Etris=-72.4,S=35,T=25){
	R  =  8.31447215 # J K–1 mol–1, Dickson et al. (2007)
	F  =  96485.339924 # C mol–1, Dickson et al. (2007)
	pH = tris(S=S, T=T) + (Etris/1000-Ex/1000)/(R*(T + 273.15)*log(10)/F)
	attr(pH,"unit") <- "mol/kg"
	attr(pH, "pH scale") <- "total scale"
	return(pH)
}