K1: First dissociation constant of carbonic acid (mol/kg)

In seacarb: Calculates parameters of the seawater carbonate system

Description

First dissociation constant of carbonic acid (mol/kg)

Usage

K1(S = 35, T = 25, P = 0, k1k2="l", pHscale="T")

Arguments

S	Salinity, default is 35
T	Temperature in degrees Celsius, default is 25°C
P	Hydrostatic pressure in bar (surface = 0), default is 0
k1k2	"l" for using K1 and K2 from Lueker et al. and "r" for using K1 and K2 from Roy et al. , default is "l"
pHscale	choice of pH scale: "T" for using the total scale, "F" for using the free scale and "SWS" for using the seawater scale, default is total scale

Details

Note that the arguments can be given as a unique number or as vectors. If the lengths of the vectors are different, the longer vector is retained and only the first value of the other vectors is used. It can therefore be critical to use vectors of the same length.

Value

K1	First dissociation constant of carbonic acid (mol/kg)

Author(s)

Héloïse Lavigne, Aurélien Proye and Jean-Pierre Gattuso [e-mail]

References

The Lueker et al. (2000) constant is recommended by Guide to Best Practices for Ocean CO2 Measurements (2007). The Roy et al. (1993) constants is recommended by DOE (1994).

Dickson A. G., Sabine C. L. and Christian J. R., 2007 Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 1-191.

DOE 1994 Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water. ORNL/CDIAC-74. Oak Ridge,Tenn.: Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory.

Lueker, T. J. Dickson, A. G. and Keeling, C. D. 2000 Ocean pCO2 calculated from dissolved inorganic carbon, alkalinity, and equations for K1 and K2: validation based on laboratory measurements of CO2 in gas and seawater at equilibrium. Marine Chemistry 70 105-119.

Roy, R. N. Roy, L. N. Vogel, K. M. Porter-Moore, C. Pearson, T. Good C. E., Millero F. J. and Campbell D. M., 1993. The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C. Marine Chemistry 44, 249-267.

See Also

K2.

Examples

  K1(S=35,T=25,P=0,k1k2="l",pHscale="T")

Example output

Loading required package: oce
Loading required package: testthat
Loading required package: gsw
[1] 1.421828e-06
attr(,"unit")
[1] "mol/kg-soln"
attr(,"pH scale")
[1] "total scale"
attr(,"method")
[1] "Luecker et al. (2000)"

seacarb documentation built on May 2, 2019, 5:34 p.m.