pTA: pTA

In seacarb: Calculates parameters of the seawater carbonate system

Description

Calculates the carbonate chemistry following addition of CO_3^{2-} or HCO_3^-

Usage

pTA(flag, sys=0, var1, var2, pCO2a, co3, hco3, S=35, T=20, P=0, Pt=0, Sit=0, k1k2="l", kf="pf", pHscale="T")

Arguments

flag	select the couple of variables available. The flags which can be used are: flag = 1 pH and CO2 given flag = 2 CO2 and HCO3 given flag = 3 CO2 and CO3 given flag = 4 CO2 and ALK given flag = 5 CO2 and DIC given flag = 6 pH and HCO3 given flag = 7 pH and CO3 given flag = 8 pH and ALK given flag = 9 pH and DIC given flag = 10 HCO3 and CO3 given flag = 11 HCO3 and ALK given flag = 12 HCO3 and DIC given flag = 13 CO3 and ALK given flag = 14 CO3 and DIC given flag = 15 ALK and DIC given flag = 21 pCO2 and pH given flag = 22 pCO2 and HCO3 given flag = 23 pCO2 and CO3 given flag = 24 pCO2 and ALK given flag = 25 pCO2 and DIC given
sys	0 if the manipulation is carried out in a system closed to the atmosphere or 1 if its is carried out in a system open to the atmosphere
var1	Value of the first variable in mol/kg, except for pH and for pCO2 in μatm
var2	Value of the second variable in mol/kg, except for pH
pCO2a	CO2 partial pressure in the atmosphere pCO2 in μatm. It is only used in systems open to the atmosphere (i.e. when sys=1)
co3	Amount of CO_3^{2-} added in mol\,kg^{-1}
hco3	Amount of HCO_3^{2-} added in mol\,kg^{-1}
S	Salinity
T	Temperature in degrees Celsius
P	Hydrostatic pressure in bar (surface = 0)
Pt	Concentration of total phosphate in mol/kg
Sit	Concentration of total silicate in mol/kg
k1k2	"l" for using K1 and K2 from Lueker et al. and "r" for using K1 and K2 from Roy and al. , default is "l"
kf	"pf" for using Kf from Perez and Fraga (1987) and "dg" for using Kf from Dickson and Goyet (1979), default is "pf"
pHscale	choice of pH scale: "T" for using the total scale, "F" for using the free scale and "SWS" for using the seawater scale, default is total scale

Value

The function returns a data frame containing the following columns:

comment	The initial or final state water
S	Salinity
T	Temperature in degrees Celsius
P	Pressure in bar
pH	pH
CO2	CO2 concentration (mol/kg)
pCO2	pCO2, CO2 partial pressure (μatm)
fCO2	fCO2, CO2 fugacity (μatm)
HCO3	HCO3 concentration (mol/kg)
CO3	CO3 concentration (mol/kg)
DIC	DIC concentration (mol/kg)
ALK	ALK, total alkalinity (mol/kg)
OmegaAragonite	Omega aragonite, aragonite saturation state
OmegaCalcite	Omega calcite, calcite saturation state

Author(s)

Jean-Pierre Gattuso [e-mail]

Examples

pTA(flag=24, sys=0, var1=384, var2=2302e-6, pCO2a=384, co3=260e-6, hco3=1000e-6, S=34.3, T=16, P=0, pHscale="T", kf="pf", k1k2="l")

pTA(flag=24, sys=1, var1=384, var2=2302e-6, pCO2a=384, co3=260e-6, hco3=1000e-6, S=34.3, T=16, P=0, pHscale="T", kf="pf", k1k2="l")

seacarb documentation built on May 2, 2019, 5:34 p.m.