Ks: Stability constant of hydrogen sulfate (mol/kg)

Description Usage Arguments Details Value Author(s) References Examples

Description

Stability constant of hydrogen sulfate (mol/kg)

Usage

1
Ks(S = 35, T = 25, P = 0)

Arguments

S

Salinity, default is 35

T

Temperature in degrees Celsius, default is 25oC

P

Hydrostatic pressure in bar (surface = 0), default is 0

Details

Note that the arguments can be given as a unique number or as vectors. If the lengths of the vectors are different, the longer vector is retained and only the first value of the other vectors is used. It can therefore be critical to use vectors of the same length.

Value

Ks

Stability constant of hydrogen sulfate (mol/kg), pHscale = free scale

Author(s)

Héloïse Lavigne, Aurélien Proye and Jean-Pierre Gattuso gattuso@obs-vlfr.fr

References

Ks is given by Dickson (1990) in Guide to Best Practices in Ocean CO2 Measurements 2007).

Dickson, A. G. 1990 Standard potential of the reaction: AgCI(s) + 1/2H2(g) = Ag(s) + HCI(aq), and the standard acidity constant of the ion HSO4 in synthetic sea water from 273.15 to 318.15 K. Journal of Chemical Thermodynamics 22, 113-127.

DOE 1994 Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water. ORNL/CDIAC-74. Oak Ridge,Tenn.: Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory.

Dickson A. G., Sabine C. L. and Christian J. R., 2007 Guide to best practices for ocean CO2 measurements. PICES Special Publication 3, 1-191.

Examples

1
  Ks(S=35,T=25,P=0)

Example output

Loading required package: oce
Loading required package: testthat
Loading required package: gsw
[1] 0.1003021
attr(,"unit")
[1] "mol/kg-soln"
attr(,"pH scale")
[1] "free scale"
attr(,"method")
[1] "Dickson (1990)"

seacarb documentation built on May 2, 2019, 5:34 p.m.

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