Description Usage Arguments Details Value Warnings Note Author(s) References Examples
Calculates water vapor pressure, given water temperature and salinity, using a variety of methods. This is required to convert partial pressure of oxygen into saturation or concentration units and vice-versa.
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t |
Temperature in °C |
s |
Salinity in parts per thousand |
method |
One of "IAPWS", "BensonKrause", "GreenCarritt","WMO2008", "Antoine", "Weiss", "GoffGratch". See Details. |
sal_method |
One of "Chabot", "Green" or "none". See Details. |
Output: water vapor pressure above fresh or sea water in kPa.
Note: this function is not intended to calculate vapor pressure above ice. Also, water vapor pressure is not affected by atmospheric pressure
Methods for vapor pressure calculation above fresh water:
This is the 'official' formulation from the International Association for the Properties of Water and Steam (Wagner & Pruss 1993), Eq. 2.5 p. 399. The valid range of this formulation is 273.16 <= K <= 647.096 and is based on the ITS90 temperature scale.
Eq. 23 of Benson and Krause, 1980
Green & Carritt 1967 (see also table 2 Benson & Krause 1984) without salinity correction, in atm converted to kPa
Annex 4B, Guide to Meteorological Instruments and Methods of Observation, WMO Publication No 8, 7th edition, Geneva, 2008.
http://www.watervaporpressure.com
Weiss & Price 1980 eq 10 p. 350, in atm converted to kPa
Smithsonian Meteorological Tables, 5th edition, p. 350, 1984, in hPa then converted to kPa
Methods for salinity correction:
My own polynomial fit passing through origin to Robinson 1954's data, Table II p. 451 gives values of delta vp for different chlorinities. Chlorinity changed into salinity according to Lyman (1969)
From table 2 in Benson & Krause (1984)
Removes salinity correction, same as leaving s
to its
default value of zero
A vector of same length as parameter t
s
must be of length 1 or same length as t. This
is not checked by the function at present so errors could occur if this is
not respected.
This assumes that air temperature above the water surface is that of the water. The effect of salinity is negligible, but it is nevertheless included in the calculation if the user provides salinity.
Denis Chabot
Benson B.B. and Krause D.Jr. (1980) The concentration and isotopic fractionation of gases dissolved in freshwater in equilibrium with the atmosphere. 1. Oxygen. Limnology and Oceanography, 25, 662-671.
Benson B.B. and Krause D.Jr. (1984) The concentration and isotopic fractionation of oxygen dissolved in freshwater and seawater in equilibrium with the atmosphere. Limnology and Oceanography, 29, 620-632.
Green, E. J. and Carritt, D. E. (1967) New tables for oxygen saturation of seawater. Journal of Marine Research, 25, 140-147.
Lyman, J. (1969) Redefinition of salinity and chlorinity. Limnology and Oceanography, 27, 928-929.
Robinson R. A. (1954) The vapour pressure and osmotic equivalence of sea water. Journal of the Marine Biological Association of the United Kingdom, 33, 449-455.
Wagner, W. and Pruss, A. (1993) International Equations for the Saturation Properties of Ordinary Water Substance. Revised According to the International Temperature Scale of 1990. Addendum to J. Phys. Chem. Ref. Data 16, 893 (1987) Journal of Physical and Chemical Reference Data, 22, 783. http://dx.doi.org/10.1063/1.555926.
Wagner, W. & Pruss, A. (2002) The IAPWS formulation 1995 for the thermodynamic properties of ordinary water substance for general and scientific use. Journal of Physical and Chemical Reference Data, 31(2), 387-535.
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