equil_frac: Liquid-vapor equilibrium fractionation
In jmerc13/LakeIsodrology: Lake isotope hydrology
Description
Usage
Arguments
Details
Value
Description
Estimates the temperature-dependent equilibrium fracitonation factor (aka,
isotope effect), α^*_{LV}, of common water isotopes (i.e.,
2-Hydrogen and 18-Oxygen) between the liquid and vapor phases.
Usage
1
equil_frac(Ta, element)
Arguments
Ta
Air temperature, T_{a} (C).
element
Character indicating "Hydrogen" or "Oxygen".
Details
Fractionations determined via (Majoube 1971):
Hydrogen: 10^{3} \ln(α^*_{LV}) = 24.844(10^{6}/(T_{a} + 273.15)^{2}) -
76.248(10^{3}/(T_{a} + 273.15)^{2}) + 52.612
Oxygen: 10^{3} \ln(α^*_{LV}) = 1.137(10^{6}/(T_{a} + 273.15)^{2}) -
0.4156(10^{3}/(T_{a} + 273.15)) - 2.0667
Majoube M. 1971. Oxygen-18 and deuterium fractionation between water and
steam (in French). Journal de Chimie Physique et de Physico-Chimie Biologique
68: 1423–1436.
Value
Numeric value of equilibrium fractionation factor from liquid
to vapor - a unitless value.
jmerc13/LakeIsodrology documentation built on May 5, 2019, 5:52 p.m.
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Description Usage Arguments Details Value
Description
Estimates the temperature-dependent equilibrium fracitonation factor (aka, isotope effect), α^*_{LV}, of common water isotopes (i.e., 2-Hydrogen and 18-Oxygen) between the liquid and vapor phases.
Usage
1 | equil_frac(Ta, element)
|
Arguments
Ta |
Air temperature, T_{a} (C). |
element |
Character indicating "Hydrogen" or "Oxygen". |
Details
Fractionations determined via (Majoube 1971):
Hydrogen: 10^{3} \ln(α^*_{LV}) = 24.844(10^{6}/(T_{a} + 273.15)^{2}) - 76.248(10^{3}/(T_{a} + 273.15)^{2}) + 52.612
Oxygen: 10^{3} \ln(α^*_{LV}) = 1.137(10^{6}/(T_{a} + 273.15)^{2}) - 0.4156(10^{3}/(T_{a} + 273.15)) - 2.0667
Majoube M. 1971. Oxygen-18 and deuterium fractionation between water and steam (in French). Journal de Chimie Physique et de Physico-Chimie Biologique 68: 1423–1436.
Value
Numeric value of equilibrium fractionation factor from liquid to vapor - a unitless value.
R Package Documentation
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Note that we can't provide technical support on individual packages. You should contact the package authors for that.
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