diwb_sa: Titration Curve for Diprotic Weak Base

In titrationCurves: Acid/Base, Complexation, Redox, and Precipitation Titration Curves

Description

This function calculates and plots the titration curve for a diprotic weak base analyte using a monoprotic strong acid as the titrant. The calculation uses a single master equation that finds the volume of titrant needed to achieve a fixed pH, as outlined in R. de Levie's Principles of Quantitative Chemical Analysis (McGraw-Hill, 1997).

Usage

diwb_sa(conc.base = 0.1, conc.acid = 0.1, pka1 = 5, pka2 = 9,
  pkw = 14, vol.base = 50, plot = TRUE, eqpt = FALSE, overlay = FALSE,
  ...)

Arguments

conc.base	Molar concentration of the diprotic weak base analyte; defaults to 0.10 M.
conc.acid	Molar concentration of the strong base titrant; defaults to 0.10 M.
pka1	The pKa1 value for the diprotic weak base analyte's conjugate weak acid; defaults to a pKa1 of 5, or a pKb2 of 9 for the weak base analyte.
pka2	The pKa2 value for the diprotic weak base analyte's conjugate weak acid; defaults to a pKa2 of 9, or a pKb1 of 5.
pkw	The pKw (or pKs) value for the solvent; defaults to water as a solvent with a pKw of 14.
vol.base	The initial volume, in mL, of the solution that contains the weak base analyte; defaults to 50.00 mL.
plot	Logical; if TRUE, plots the titration curve.
eqpt	Logical; if TRUE, draws a vertical line at the titration curve's equivalence point.
overlay	Logical; if TRUE, adds the current titration curve to the existing titration curve.
...	Additional arguments to pass to plot() function.

Value

A two-column data frame that contains the volume of titrant in the first column and the solution's pH in the second column. Also produces a plot of the titration curve with options to display the equivalence point and to overlay titration curves.

Author(s)

David T. Harvey, DePauw University. [e-mail]

Examples

### Simple titration curve with equivalence points
ex6 = diwb_sa(eqpt = TRUE)
head(ex6)

### Overlay titration curves using different pKa1 and pKa2 values
diwb_sa(pka1 = 5, pka2 = 9, eqpt = TRUE)
diwb_sa(pka1 = 6, pka2 = 10, overlay = TRUE)
diwb_sa(pka1 = 4, pka2 = 8,  overlay = TRUE)

Example output

      volume    ph
1 0.01767360 10.99
2 0.04025902 10.98
3 0.06286702 10.97
4 0.08550889 10.96
5 0.10819592 10.95
6 0.13093942 10.94

titrationCurves documentation built on May 2, 2019, 12:56 a.m.