Description Usage Arguments Value Author(s) Examples
This function calculates and plots the titration curve for a monoprotic weak base analyte using a monoprotic strong acid as the titrant. The calculation uses a single master equation that finds the volume of titrant needed to achieve a fixed pH, as outlined in R. de Levie's Principles of Quantitative Chemical Analysis (McGraw-Hill, 1997).
1 2 |
conc.acid |
Molar concentration of the strong acid titrant; defaults to 0.10 M. |
conc.base |
Molar concentration of the weak base analyte; defaults to 0.10 M. |
pka |
The pKa value for the weak base analyte's conjugate weak acid; defaults to a pKa of 9, or a pKb of 5 for the weak base analyte. |
pkw |
The pKw (or pKs) value for the solvent; defaults to water as a solvent with a pKw of 14. |
vol.base |
Initial volume, in mL, of the solution that contains the weak base analyte; defaults to 50.00 mL. |
plot |
Logical; if TRUE, plots the titration curve. |
eqpt |
Logical; if TRUE, draws a vertical line at the titration curve's equivalence point. |
overlay |
Logical; if TRUE, adds the current titration curve to the existing titration curve. |
... |
Additional arguments to pass to |
A two-column data frame that contains the volume of titrant in the first column and the solution's pH in the second column. Also produces a plot of the titration curve with options to display the equivalence point and to overlay titration curves.
David T. Harvey, DePauw University. harvey@depauw.edu
1 2 3 4 5 6 7 8 9 10 11 12 | ### Simple titration curve with equivalence point
ex4 = wb_sa(eqpt = TRUE)
head(ex4)
### Overlay titration curves using different pKa values
wb_sa(pka = 9, eqpt = TRUE)
wb_sa(pka = 7, overlay = TRUE)
wb_sa(pka = 5, overlay = TRUE)
### Overlay titration curve for strong base and weak base
sb_sa(eqpt = TRUE)
wb_sa(overlay = TRUE)
|
volume ph
1 0.01767258 10.99
2 0.04025795 10.98
3 0.06286590 10.97
4 0.08550772 10.96
5 0.10819469 10.95
6 0.13093813 10.94
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